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I am not entirely sure if you mean the actual SD-card itself or the OS on it, but I'll answer both just in case: You can't use Raspberry Pi's Raspbian, you have install the Orange Pi - specific version of Raspbian on the SD-card from the downloads - section, but as for the actual physical card itself -- it shouldn't matter what the physical card is as long as it's not broken. As for the LED: I am not sure, I am still waiting for my own Pi to arrive in the mail, but I think I read in another post that the LEDs don't come on if there is no bootable SD-card in there.
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